Flow battery technologies are transforming grid-scale energy storage by offering a highly scalable solution for long-duration energy storage (LDES). Unlike conventional batteries, flow systems decouple power and energy by storing liquid electrolytes in external tanks, allowing utilities to increase storage capacity simply by sizing up the tanks. While vanadium redox systems lead the market with exceptional cycle life and zero degradation, active research into iron-air, zinc-bromine, and organic chemistries is rapidly driving down upfront costs. Consequently, flow batteries are becoming vital for stabilizing grids, smoothing out intermittent wind and solar power, and ensuring long-term energy security worldwide.